化學(xué)名 |
2,5-Furandimethanol,a2-[3-[6-(5-bromotetrahydro-2,6,6-trimethyl-2H-pyran-2-yl)octahydro-8a-methylpyrano[3,2-b]pyran-2-yl]-3-hydroxybutyl]tetrahydro-a5,a5,2-trimethyl-,[2R-[2α[S*[R*(2R*,5S*)]],4aβ,6α(2S*,5R*,8aα)]]-
|
理化性質(zhì) |
白色固體,mp161.5℃;160~161℃,[α]20/D+9.4°(c=3.2,氯仿)。IR γmax(KBr)cm\-1:3360,2960,1445,1370,1173,1118,1095,1083,1015;(CHCl3):3420,2960,1460,1375,1100。FDMS;EIMSm/z(re1.int.):588(1.2),586(M+-H2O,1.1),570(0.7),568(0.7),552(0.9),550(0.9),529(1.1),527(1.1),524(2.8),506(6),491(6),486(6),470(2.8),445(3.8),443(3.7),409(5),363(10),227(78),209(75),207(25),205(26),193(11),165(10),127(42),125(100),111(31),109(40),107(40)。1HNMR。13CNMR。X-ray。
|